European Classic team:
Win the European Cup as England.

Holland Classic team:
Win the European Cup as Holland.

Germany Classic team:
Win the European Cup as Germany.

Brazil Classic team:
Win the American Cup as Brazil.

Argentina Classic team:
Win the American Cup as Argentina.

World All-Star team:
Win the International Cup as any team.

European All-Star team:
Win the International Cup as France.

Bonus players:
Win the Division 1 Master League to unlock 11 bonus players in freeloan mode. Repeat this two more times to unlock all 33 bonus players.

Win a Master League A season to unlock bonus players. They can be bought at the freelance players block.

Winners cup:
Win all cups, leagues, and Division 1 Master League.

Get all Players at 99 [Submitted by: James Pickering]
To get all players at 99 go to formation hold down Square and type Up, Up, Up, Up, Up, Left, Right, Right, Right